2D Violet phosphorene with highly anisotropic mobility and its vdW heterojunction design for device applications. Issue 5 (24th January 2022)

• Record Type: Journal Article
• Authors: Xu, Yuehua; Long, Qianqian; Li, Dongze; Li, Pengfei
• Is Part Of: Physical chemistry chemical physics. Volume 24:Issue 5(2022)
• Page Start: 3379
• Page End: 3385
• Publication Date: 2022-01-24
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/d1cp04810d
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : A 2D violet phosphorene monolayer with high anisotropic carrier mobility and a graphene/violet phosphorene vdW heterojunction with tailoring of the Schottky/ohmic contact. Abstract : Recently, the crystal structure of violet phosphorus and its monolayer violet phosphorene (VP) have been reconfirmed experimentally, and they were verified to be more thermally stable than their allotrope, black phosphorus. Here, we calculated the carrier mobility of monolayer VP using density functional theory. It is found that the carrier mobility is highly anisotropic and the hole mobility reaches 9.86 × 10 3 cm 2 V −1 s −1 in the a -direction, endowing the potential application of VP in p-type semiconductor channel materials. Moreover, the Schottky barrier of the graphene/VP heterojunction turns into an ohmic contact when the electric field strength is >2 V nm −1 . Therefore, VP and graphene/VP heterojunctions have potential prospects in electronic devices.