Direct conversion X-ray detectors with 70 pA cm−2 dark currents coated from an alcohol-based perovskite ink. Issue 4 (4th January 2022)

• Record Type: Journal Article
• Authors: Li, Yunlong; Adeagbo, Emmanuel; Koughia, Cyril; Simonson, Blaine; Pettipas, Richard D.; Mishchenko, Anastasiia; Arnab, Salman M.; Laperrière, Luc; Belev, George; Stevens, Amy L.; Kasap, Safa O.; Kelly, Timothy L.
• Is Part Of: Journal of materials chemistry. Volume 10:Issue 4(2022)
• Page Start: 1228
• Page End: 1235
• Publication Date: 2022-01-04
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d1tc05338h
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : A poly(methyl methacrylate) blocking layer was found to reduce the dark current density in CH3 NH3 PbI3 -based direct-conversion X-ray detectors to as low as 70 pA cm −2 . Abstract : Direct conversion X-ray image detectors offer higher spatial resolution than their indirect counterparts. Organic–inorganic hybrid perovskites are among the most sensitive X-ray photoconductors for these detectors; however, high dark currents make it difficult for perovskites to compete with commercial amorphous selenium (a-Se) technology. Here we report a simple perovskite ink formulation that uses environmentally friendly 85% ethanol as the solvent. The ink was used to blade-coat thick perovskite films, which when combined with poly(methyl methacrylate) (PMMA) blocking layers, produce direct conversion detectors with dark currents ∼70 pA cm −2 . These dark currents are two to three orders of magnitude lower than those of other perovskite-based detectors and are comparable to those of commercial a-Se devices. Other device figures-of-merit, including X-ray sensitivity and mobility-lifetime ( μτ ) product, are superior to those of commercial a-Se detectors. Our results demonstrate how to effectively suppress the dark current in perovskite photoconductive X-ray detectors, paving the way for low-dose mammography and radiography.