Migration behavior and leaching ability of radioactive uranium during incineration of uranium-containing strippable coating wastes. (1st April 2022)

• Record Type: Journal Article
• Authors: Zhang, Kun; Wang, Lizi; Chen, Wenzhuo; Li, Zhanguo; Qi, Sheng; Li, Daxue; Li, Yintao; Wang, Shanqiang; Yang, Jigang
• Is Part Of: Journal of environmental management. Volume 307(2022)
• Publication Date: 2022-04-01
• Subjects: Strippable coating -- Uranium -- Incineration -- Migration -- Leaching; Environmental policy -- Periodicals; Environmental management -- Periodicals; Environment -- Periodicals; Ecology -- Periodicals; 363.705
• DOI: 10.1016/j.jenvman.2022.114583
• Languages: English
• ISSNs: 0301-4797

Abstract

Abstract: It is currently thought that the incineration approach is an effective method to minimize the volume of radioactive wastes. In this paper, we used an incinerator to burn uranium-containing strippable coating waste. The migration behavior of radioactive uranium during the incineration process were investigated based on hierarchical sampling and mass spectrometry. Results shows that the radioactive uranium is more easily to adhere to the particles with smaller size. The leaching abilities of radioactive uranium in the bottom ash and the fly ash were analyzed. The leaching rate of the uranium from the fly ash and bottom ash were 1% and 6%, respectively, indicating that most of the radioactive uranium was fixed in the ash and the same storage/disposal methods can be used for both the fly ash and bottom ash. According to x-ray spectrometry and SEM-EDS, mineral compositions of the original uranium ore and the bottom ash were mostly the same. Calcium plays an important role in uranium fixation during incineration. The potential mechanism of the uranium special transformation during uranium-containing strippable coating waste combustion was revealed. Our research results can provide technical support for nuclear emergency waste treatment and disposal. Highlights: The smaller the size, the greater the adherence of the radioactive uranium particles. Near 85% of radioactive uranium particles fixed in bottom ash. Radioactive uranium particles leach better in bottom than in flying ash. Alkali elements improve uranium fixation.