Advances in allylic and benzylic C–H bond functionalization enabled by metallaphotoredox catalysis. Issue 2 (9th December 2021)

• Record Type: Journal Article
• Authors: Yue, Huifeng; Zhu, Chen; Huang, Long; Dewanji, Abhishek; Rueping, Magnus
• Is Part Of: Chemical communications. Volume 58:Issue 2(2022)
• Page Start: 171
• Page End: 184
• Publication Date: 2021-12-09
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d1cc06285a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Merging two powerful methodologies, metallaphoto-catalyzed benzylic and allylic C(sp 3 )–H bond functionalizations provide a series of general and mild approaches for diversification of alkylbenzenes and alkenes. Abstract : Metallaphoto-catalysis has been established as a robust platform for efficient construction of a range of chemical bonds. Moreover, transformation of native functionalities such as C(sp 3 )–H bonds to produce functional molecules represents one of the most attractive strategies in organic synthesis. Merging two powerful methodologies, metallaphoto-catalyzed benzylic and allylic C(sp 3 )–H bond functionalizations provide a series of general and mild approaches for diversification of alkylbenzenes and alkenes.