Application of Hi-throat/Hi-volume SPE technique in assessing organophosphorus pesticides and their degradation products in surface water from Tai Lake, east China. (1st March 2022)

• Record Type: Journal Article
• Authors: Wei, Lai; Zhu, Ningzheng; Liu, Xuan; Zheng, Hongyuan; Xiao, Kaiyan; Huang, Qinghui; Liu, Hongling; Cai, Minghong
• Is Part Of: Journal of environmental management. Volume 305(2022)
• Publication Date: 2022-03-01
• Subjects: Organophosphorus pesticides -- Degradation product -- East China -- Ecological risk; Environmental policy -- Periodicals; Environmental management -- Periodicals; Environment -- Periodicals; Ecology -- Periodicals; 363.705
• DOI: 10.1016/j.jenvman.2021.114346
• Languages: English
• ISSNs: 0301-4797

Abstract

Abstract: Organophosphorus pesticides (OPPs) are among the most commonly used pesticides worldwide. However, these compounds pose a serious threat to aquatic environments. Here, thirty-seven pesticides and eight degradation products were determined in surface water samples from Tai Lake, East China, using a high-volume solid phase extraction technique (Hi-throat/Hi-volume SPE). Surface water was pumped in-situ through a portable sampler, and OPPs in the water retained on the Hi-volume SPE adsorption column, finally extracted for analysis. This technique efficiently reduced the detection limits to below 0.3 ng/L. In total, 40 out of 45 OPP congeners were detected, which far exceeded the amount of OPPs in previous studies. The total concentration of OPPs ranged between 101.4 and 1530 ng/L (median: 378.9 ng/L). Parathion exhibited the highest concentration (median: 112.0 ng/L), followed by paraoxon-methyl (median: 90.3 ng/L), as well as carbophenothion, fenthion, and mevinphos. Agricultural areas were more polluted than residential and industrial regions. However, degradation products persisted in residential and industrial waters. The ecological risks of OPPs in these areas were estimated based on the risk quotient index (RQ). Parathion, fenthion, carbophenothion, and tolclofos-methyl occurred at high-risk levels, and the levels of degradation products were also non-trivial. Our findings thus indicated that OPP degradation products pose a potential threat to natural environments and should therefore be closely monitored. Graphical abstract: Image 1 Highlights: Hi-throat/Hi-volume SPE technique was efficiently applied in assessing OPPs. OPPs and degradation products detected in surface water of East China. Degradation products persist in industrial and residential waters. Parathion, fenthion, carbophenothion, and tolclofos methyl exhibited high risk. Threating degradation products of OPPs needed further management.