Enantioselective Radical Addition/Cross‐Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenyl Boron Reagents. (28th August 2019)
- Record Type:
- Journal Article
- Title:
- Enantioselective Radical Addition/Cross‐Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenyl Boron Reagents. (28th August 2019)
- Main Title:
- Enantioselective Radical Addition/Cross‐Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenyl Boron Reagents
- Authors:
- Chierchia, Matteo
Xu, Peilin
Lovinger, Gabriel J.
Morken, James P. - Abstract:
- Abstract: A hybrid transition‐metal/radical process is described that results in the addition of organozinc reagents and alkyl halides across alkenyl boron reagents in an enantioselective catalytic fashion. The reaction can be accomplished both intermolecularly and intramolecularly, providing useful product yields and high enantioselectivities in both manifolds. Abstract : Radikal‐Hybrid : Die Dicarbofunktionalisierung von VinylB(pin) gelang mit einem chiralen Nickel‐Katalysator. Unter Verwendung eines Alkylhalogenids und Organozink‐Reagentien wurden bei intra‐ oder intermolekularer Reaktionsführung hohe Enantioselektivitäten erzielt.
- Is Part Of:
- Angewandte Chemie. Volume 131:Number 40(2019)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 131:Number 40(2019)
- Issue Display:
- Volume 131, Issue 40 (2019)
- Year:
- 2019
- Volume:
- 131
- Issue:
- 40
- Issue Sort Value:
- 2019-0131-0040-0000
- Page Start:
- 14383
- Page End:
- 14387
- Publication Date:
- 2019-08-28
- Subjects:
- Bor -- Katalyse -- Kreuzkupplungen -- Nickel -- Radikalreaktionen
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201908029 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 20461.xml