Scanning Electrochemical Cell Microscopy Investigation of Single ZIF‐Derived Nanocomposite Particles as Electrocatalysts for Oxygen Evolution in Alkaline Media. Issue 40 (21st August 2019)

• Record Type: Journal Article
• Authors: Tarnev, Tsvetan; Aiyappa, Harshitha Barike; Botz, Alexander; Erichsen, Thomas; Ernst, Andrzej; Andronescu, Corina; Schuhmann, Wolfgang
• Is Part Of: Angewandte Chemie international edition. Volume 58:Issue 40(2019)
• Page Start: 14265
• Page End: 14269
• Publication Date: 2019-08-21
• Subjects: electrocatalysis -- metal–organic frameworks -- nanoparticles -- oxygen evolution reaction -- scanning electrochemical cell microscopy; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201908021
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: "Single entity" measurements are central for an improved understanding of the function of nanoparticle‐based electrocatalysts without interference arising from mass transfer limitations and local changes of educt concentration or the pH value. We report a scanning electrochemical cell microscopy (SECCM) investigation of zeolitic imidazolate framework (ZIF‐67)‐derived Co−N‐doped C composite particles with respect to the oxygen evolution reaction (OER). Surmounting the surface wetting issues as well as the potential drift through the use of a non‐interfering Os complex as free‐diffusing internal redox potential standard, SECCM could be successfully applied in alkaline media. SECCM mapping reveals activity differences relative to the number of particles in the wetted area of the droplet landing zone. The turnover frequency (TOF) is 0.25 to 1.5 s −1 at potentials between 1.7 and 1.8 V vs. RHE, respectively, based on the number of Co atoms in each particle. Consistent values at locations with varying number of particles demonstrates OER performance devoid of macroscopic film effects. Abstract : The oxygen evolution reaction (OER) activity of single and multiple ZIF‐derived Co/N−C nanocomposite particles was examined by high‐throughput scanning electrochemical cell microscopy. Through the use of an Os complex as an internal reference standard, the intrinsic activity of the catalyst with respect to the OER activity as well as the turnover frequency could be determined.