Direct Production of Higher Oxygenates by Syngas Conversion over a Multifunctional Catalyst. Issue 14 (28th February 2019)

• Record Type: Journal Article
• Authors: Lin, Tiejun; Qi, Xingzhen; Wang, Xinxing; Xia, Lin; Wang, Caiqi; Yu, Fei; Wang, Hui; Li, Shenggang; Zhong, Liangshu; Sun, Yuhan
• Is Part Of: Angewandte Chemie international edition. Volume 58:Issue 14(2019)
• Page Start: 4627
• Page End: 4631
• Publication Date: 2019-02-28
• Subjects: cobalt carbide -- higher oxygenates -- olefins -- synergetic effect -- syngas conversion; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201814611
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Selective synthesis of higher oxygenates (linear α‐alcohols and α‐aldehydes, C 2 + OH) from syngas is highly attractive but remains challenging owing to the low C 2 + OH selectivity and low catalytic stability. Herein we introduce a multifunctional catalyst composed of CoMn and CuZnAlZr oxides that dramatically increased the oxygenates selectivity to 58.1 wt %, where more than 92.0 wt % of the produced oxygenates are C 2 + OH. Notably, the total selectivity to value‐added chemicals including oxygenates and olefins reached 80.6 wt % at CO conversion of 29.0 % with high stability. The appropriate component proximity can effectively suppress the formation of the undesired C1 products, and the selectively propulsion of reaction network by synergetic effect of different components contributes to the enhanced selectivity to higher oxygenates. This work provides an alternative strategy for the rational design of new catalysts for direct conversion of syngas into higher oxygenates with co‐production of olefins. Abstract : A stable multifunctional catalyst composed of CoMn oxides and CuZnAlZr oxides was developed for direct conversion of syngas to higher oxygenates and olefins with a total selectivity of 80.6 wt % at a CO conversion of 29.0 %. The interaction manner of the two components plays a crucial role in suppressing C1 products formation and enhancing the selectivity to higher oxygenates.