Exfoliated Metal Oxide Nanosheets as Effective and Applicable Substrates for Atomically Dispersed Metal Nanoparticles with Tailorable Functionalities. Issue 20 (7th September 2016)

• Record Type: Journal Article
• Authors: Seo, Jiyoon; Jin, Xiaoyan; Kim, Minho; Kim, In Young; Jo, Yun Kyung; Bera, Sandipan; Lee, Nam‐Suk; Lee, Wan In; Kim, Hyungjun; Hwang, Seong‐Ju
• Is Part Of: Advanced materials interfaces. Volume 3:Issue 20(2016)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2016-09-07
• Subjects: atomically dispersed metal nanoparticles -- controlled crystal growth -- functionality -- inorganic nanosheet -- surface structure; Materials science -- Periodicals; 620.11
• DOI: 10.1002/admi.201600661
• Languages: English
• ISSNs: 2196-7350

Abstract

Abstract : An effective methodology to stabilize highly dispersed metal nanoparticles is developed by employing the exfoliated 2D metal oxide nanosheets with variable surface structures as substrates. The selection of appropriate crystal structure of titanate nanosheet is very crucial in stabilizing atomically dispersed Pt nanoparticles through the tuning of chemical interaction between Pt and titanate substrate. A theoretical study using density functional theory calculations confirms the significant influence of the crystal structure of layered titanate nanosheet on the crystal growth behavior of immobilized metal nanoparticle. As a consequence of the good dispersion of Pt nanoparticles, the Pt–trititanate nanohybrids with stronger interaction show much higher content of atomically dispersed Pt and better catalyst performances than do the Pt–lepidocrocite titanate ones. The applicability of the present method for other metal species is evidenced by the successful tuning of the crystal size and functionality of Au nanoparticles via immobilization on layered titanate nanosheets. The functionality of Au for surface‐enhanced Raman spectroscopy becomes improved by the anchoring on the lepidocrocite‐type titanate nanosheet. The present study underscores that the use of the metal oxide 2D nanosheets with appropriate surface structure as substrates is effective in tailoring the crystal growth and the functionalities of immobilized metal nanoparticles. Abstract : An efficient methodology to tailor the crystal growth and functionality of highly dispersed metal nanoparticle is developed by employing exfoliated inorganic nanosheets as substrates. The selection of appropriate crystal structure of substrate nanosheet is fairly crucial in stabilizing atomically dispersed metal nanoparticles and also in optimizing their functionalities through the control of chemical interaction between metal and nanosheet.