Strategic Preparation of Efficient and Durable NiCo Alloy Supported N‐Doped Porous Graphene as an Oxygen Evolution Electrocatalyst: A Theoretical and Experimental Investigation. Issue 20 (30th August 2016)

• Record Type: Journal Article
• Authors: Singh, Santosh K.; Kumar, Deepak; Dhavale, Vishal M.; Pal, Sourav; Kurungot, Sreekumar
• Is Part Of: Advanced materials interfaces. Volume 3:Issue 20(2016)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2016-08-30
• Subjects: density functional theory (DFT) -- electrocatalyst -- electron density -- oxygen evolution reaction -- porous N‐doped graphene; Materials science -- Periodicals; 620.11
• DOI: 10.1002/admi.201600532
• Languages: English
• ISSNs: 2196-7350

Abstract

Abstract : Development of an efficient and durable water splitting electrocatalyst holds a great commitment for the future energy devices. The real application of oxygen evolution reaction (OER) catalysts mainly suffers from sluggish kinetics and high overpotential except for the Ir and Ru‐based systems. However, the high cost and vulnerability of the Ir and Ru metals are the main hostiles to use them for marketization. Herein, a high‐performance OER electrocatalyst consisting of NiCo alloy nanoparticles supported on high surface area N‐doped porous graphene (NiCo/pNGr(75:25)) is reported. The importance of the doped‐N for achieving the uniform dispersion‐cum‐effective interaction of the size controlled NiCo alloy nanoparticles has been explicitly investigated by transmission electron microscopy, X‐ray diffraction, X‐ray photo­electron spectroscopy, Raman, density functional theory (DFT) calculations, etc. The electrochemical analysis of NiCo/pNGr(75:25) shows an overpotential of ≈260 mV at 10 mA cm −2 with a smaller Tafel slope of ≈87 mV dec −1 and long catalytic durability. DFT calculations are done to check the interaction between the NiCo alloy nanoparticles and the defective sites of pNGr and also with the doped‐N, which could be attained for maintaining long catalytic durability. Furthermore, NiCo/pNGr(75:25) is used as an OER catalyst to fabricate an electrolyzer, which works at very low potential of 1.5 V in 1 m KOH. Abstract : NiCo bimetallic alloy nanoparticles supported on porous N‐doped graphene (NiCo/pNGr (75:25)) shows improved water splitting reaction at low overpotential of 260 mV@10 mA cm –2 . The catalytic activity is credited to the porosity of graphene, presence of doped‐N and presence of active metal alloy. The effectual metal alloy‐conducting support interaction has been studied using the density functional theory calculations.