Reversible structural transition of two-dimensional copper selenide on Cu(111). (15th December 2021)

• Record Type: Journal Article
• Authors: Zhuang, Yuan; Que, Yande; Xu, Chaoqiang; Liu, Bin; Xiao, Xudong
• Is Part Of: Nanotechnology. Volume 33:Number 9(2022)
• Publication Date: 2021-12-15
• Subjects: reversible -- structural transition -- 2D copper selenide -- Cu(111); Nanotechnology -- Periodicals; Nanotechnology -- Periodicals; Nanotechnology; Publications périodiques; Nanotechnologies; Periodicals; 620.5
• DOI: 10.1088/1361-6528/ac3d60
• Languages: English
• ISSNs: 0957-4484

Abstract

Abstract: Structural engineering opens a door to manipulating the structures and thus tuning the properties of two-dimensional materials. Here, we report a reversible structural transition in honeycomb CuSe monolayer on Cu(111) through scanning tunneling microscopy and Auger electron spectroscopy (AES). Direct selenization of Cu(111) gives rise to the formation of honeycomb CuSe monolayers with one-dimensional moiré structures (stripe-CuSe), due to the asymmetric lattice distortions in CuSe induced by the lattice mismatch. Additional deposition of Se combined with post annealing results in the formation of honeycomb CuSe with quasi-ordered arrays of triangular holes (hole-CuSe), namely, the structural transition from stripe-CuSe to hole-CuSe. Further, annealing the hole-CuSe at higher temperature leads to the reverse structural transition, namely from hole-CuSe to stripe-CuSe. AES measurement unravels the Se content change in the reversible structural transition. Therefore, both the Se coverage and annealing temperature play significant roles in the reversible structural transition in CuSe on Cu(111). Our work provides insights in understanding of the structural transitions in two-dimensional materials.