Understanding correlation of the interaction between nickel and alumina with the catalytic behaviors in steam reforming and methanation. (15th August 2019) - Zhang, Zhanming
Graphical abstract: Highlights: Interaction between Ni and Al2 O3 impacts more on catalytic activity than Ni dispersion. Weak interaction between Ni and Al2 O3 help to free Ni for catalytic reactions. Weak interaction between Ni and Al2 O3 facilitates migration and sintering of nickel. DRIFTS study show the interaction affects formation of the reaction intermediates. The interaction affects thermal stability, structures and forms of the coke deposit. Abstract: This study focused on the impacts of the varied extent of interaction between nickel and alumina in Ni/Al2 O3 on the catalytic behaviors and reaction intermediates formed in methanation of CO2 and steam reforming of acetic acid. The calcination of alumina at high temperature eliminated some "reactive sites", alleviating the interaction between nickel species and alumina and significantly impacting the catalytic activities. The interaction between nickel and alumina was much stronger and the nickel dispersion was also higher over the 5% Ni/Al2 O3 -600 °C than over 5% Ni/Al2 O3 -1000 °C. However, the activities of the former catalyst was remarkably lower. The interaction between nickel and alumina played more profound influence than nickel dispersion on the catalytic activity. The weak interaction between nickel and alumina would help to "release" or "free" the nickel species for catalytic reactions, which, however, facilitated the migration and sintering of nickel. The in situ DRIFTS studies of methanation showed that the weaker interaction between alumina and nickel promoted the conversion of HCOO *, a key intermediate from methanation of CO2, to CH4 . The properties of coke formed in steam reforming was also affected by the interaction between nickel and alumina. Fibrous form and amorphous form of coke tended to form over the catalyst with stronger interaction, while carbon nanotube tended to form over the catalyst with weaker interaction.