Synthesis of new poly(itaconate)s containing nitrile groups as high dipolar moment entities for the development of dipolar glass polymers with increased dielectric constant. Thermal and dielectric characterization. (May 2019)

• Record Type: Journal Article
• Authors: Bonardd, Sebastian; Alegria, Ángel; Saldías, Cesar; Leiva, Ángel; Kortaberria, Galder
• Is Part Of: European polymer journal. Volume 114(2019)
• Page Start: 19
• Page End: 31
• Publication Date: 2019-05
• Subjects: Polymer dielectrics -- Dipolar glass polymer -- Polyitaconates -- Dielectric constant -- Broadband dielectric spectroscopy -- Energy storage; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; Polymerization; Polymers; Periodicals; Electronic journals; 547.705
• DOI: 10.1016/j.eurpolymj.2019.02.013
• Languages: English
• ISSNs: 0014-3057

Abstract

Graphical abstract: Highlights: First time synthesis of poly(itaconate) with two nitrile groups. Use of functional groups with high dipole moment leads to increased dielectric constant values. High dielectric constant values among 7 and 13 (25 °C and 1 Hz) with relative low loss. Can be taken into consideration as potential candidates for dielectric materials. Abstract: This work presents the synthesis of new poly(itaconate)s containing one or two nitrile pendant groups through conventional radical polymerization. To the best of our knowledge, this is the first time in which the synthesis of poly(itaconate)s containing nitrile groups is reported in the literature. The effect of nitrile groups on the main properties is analyzed. Polymer structures were confirmed by Fourier transform infrared spectroscopy (FTIR), 1 H and 13 C NMR. Molecular weights were measured by size exclusion chromatography (SEC), while thermal characterization was achieved by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Dielectric properties were measured using broadband dielectric spectroscopy at different temperatures. Polymers with one or two nitrile groups presented dielectric constant values (at 25 °C and 1 kHz) of around 7 and 12.5, respectively, with relatively low dielectric losses with values below 0.02. BDS measurements showed notorious sub-glass transitions attributed to the movement of the dipolar groups under the electric field, even below −100 °C, allowing to achieve dielectric constant values above the average for polymers even at extremely low temperatures. Therefore, these materials could be considered as good candidates for energy storage applications.