Protrudent Iron Single‐Atom Accelerated Interfacial Piezoelectric Polarization for Self‐Powered Water Motion Triggered Fenton‐Like Reaction. Issue 2 (27th November 2021)

• Record Type: Journal Article
• Authors: Lan, Shenyu; Jing, Binghua; Yu, Chuan; Yan, Dengming; Li, Zhi; Ao, Zhimin; Zhu, Mingshan
• Is Part Of: Small. Volume 18:Issue 2(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-11-27
• Subjects: piezoelectric polarization -- protrudent iron single‐atoms -- self‐powered Fenton‐like reaction -- water motion -- water purification; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.202105279
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract: Water in motion presented in natural systems contains a rich source of renewable mechanical energy. Harvesting this water energy to trigger the generation of reactive oxygen species (ROS) for water purification is a desirable yet underexplored solution. Herein, the authors report a self‐powered water motion triggered Fenton‐like reaction system for wastewater treatment through the piezo‐activation of peroxymonosulfate (PMS). Isolated protrudent Fe single atomic sites are immobilized on the surface of molybdenum disulfide (MoS2 ) nanosheet to improve piezoelectric polarization of MoS2, to accelerate piezoelectric charge separation, and to enhance PMS activation for water purification. ROS ( OH, SO4 −, O2 −, and 1 O2 ) generation for PMS piezo‐activation are observed, and different water contaminants, including antibiotic, industrial chemicals, and dyes are efficiently removed under the natural water fluid. Aimed at solving concurrent issues of environmental pollution and energy crisis, this study provides a pathway for single atomic‐mediated piezo‐activation of Fenton‐like reactions through ambient self‐powered water motion for water purification. Abstract : Harvesting water motions energy to trigger piezo‐activation of peroxymonosulfate by protrudent Fe atomic sites immobilized on MoS2 for wastewater treatment is reported under natural water fluid. The investigation provides a pathway for single atomic‐mediated self‐powered piezo‐activation of Fenton‐like reactions by harnessing ambient energy from the water flow of simulated water drainage to purify wastewater.