Flexible vacancy-mediated MoS2-x nanosheet arrays for solar-driven interfacial water evaporation, photothermal-enhanced photodegradation, and thermoelectric generation. (15th January 2022)

• Record Type: Journal Article
• Authors: Yuan, Baohua; Yang, Lixia; Yang, Huawei; Bai, Liangjiu; Wang, Wenxiang; Wei, Donglei; Liang, Ying; Chen, Hou
• Is Part Of: Energy conversion and management. Volume 252(2022)
• Publication Date: 2022-01-15
• Subjects: MoS2 nanosheet -- S vacancy -- Photothermal photocatalysis -- Solar-driven interfacial water evaporation -- Thermoelectric generation; Direct energy conversion -- Periodicals; Energy storage -- Periodicals; Energy transfer -- Periodicals; Énergie -- Conversion directe -- Périodiques; Direct energy conversion; Periodicals; 621.3105
• DOI: 10.1016/j.enconman.2021.115070
• Languages: English
• ISSNs: 0196-8904

Abstract

Graphical abstract: Highlights: Vertically aligned MoS2-x nanosheet arrays were in situ grown on Mo meshes. The positive impact of interfacial heat on photocatalysis was proved. 3D solar absorber led to 0.45 kg m –2 h −1 enhancement in evaporation rate. Continuous power generation was achieved by the MoS2-x nanosheet arrays. Abstract: Integrating new functionalities into solar-driven interfacial evaporation systems has received considerable attention. Herein, a high solar energy utilization system was accomplished by using vertically aligned MoS2-x nanosheet arrays with S vacancies (MoS2-x NSAs) in situ grown on Mo meshes as solar absorbers. In this system, interfacial heat was used to drive water evaporation and photothermal-enhanced photodegradation, and the produced waste low-grade heat was converted to electricity simultaneously. The MoS2-x NSAs possessed a solar absorptance of 94.2%, favorable photothermal conversion, and heat localization properties. The localized heat and S vacancies collaboratively improved the photodegradation performance by boosting the separation of photogenerated carriers, which avoided dye accumulation on the surface of the MoS2-x NSAs during a long-term operation. Furthermore, the solar absorber with flexible and shape adaptiveness was greatly feasible for enhancing solar evaporating performance or integrating different functionalities. Specifically, a 0.45 kg m –2 h −1 increase in evaporation rate was achieved by the three-dimensional (3D) U-shaped MoS2-x NSAs in comparison with the two-dimensional (2D) counterpart. And the 3D U-shaped MoS2-x NSAs coupled with a thermoelectric module could uninterruptedly convert waste heat to electricity all day. This study successfully introduced photocatalysis and light-induced thermoelectricity into state-of-art solar-driven interfacial evaporation systems, which broadened this technology's application.