A new model for thermal conductivity of "continuous matrix / dispersed and separated 3D-particles" type composite materials and its application to WC-M (M = Co, Ag) systems. (20th January 2022)

• Record Type: Journal Article
• Authors: Wen, Shiyi; Du, Yong; Tan, Jing; Liu, Yuling; Zhou, Peng; Long, Jianzhan; Kaptay, George
• Is Part Of: Journal of materials science & technology. Volume 97(2022)
• Page Start: 123
• Page End: 133
• Publication Date: 2022-01-20
• Subjects: Thermal conductivity -- WC-Co -- WC-Ag -- Modeling -- Cemented carbides -- Composite materials; Metals -- Periodicals; Materials science -- Periodicals; Materials science; Metals; Periodicals; 620.1105
• DOI: 10.1016/j.jmst.2021.04.036
• Languages: English
• ISSNs: 1005-0302

Abstract

Highlights: A new model for obtaining thermal conductivity of composite materials is developed. The model includes all key factors i.e. grain size, composition and temperature. The thermal conductivities for WC-Co and WC-Ag systems are evaluated by the model. For the first time, the thermal conductivity of pure WC is obtained. The model contributes to designing materials with a desirable thermal conductivity. Abstract: In the present work a new thermal conductivity model is developed for two-phase composite materials, which are consisted of a continuous matrix and dispersed 3D-particles separated from each other by the matrix as a function of grain size and volume ratio of the dispersed particles at different temperatures. The model is applied to reproduce experimental thermal conductivity values of cemented carbide systems WC-Co and WC-Ag. Good agreement was found between measured thermal conductivity data originating from both this work and recent literature and the calculated ones only using semi-empirical parameters for the interfacial thermal resistance (ITR) values at WC/Co, WC/Ag and WC/WC interfaces as a function of temperature. Additionally, the temperature and grain size dependence of the thermal conductivity for WC is established for the first time. The model works well for the case when the matrix (Ag) has a higher thermal conductivity compared to that of the WC particles and also for the case when the matrix (Co) has a lower thermal conductivity compared to that of the WC particles. The new model forms a physically sound basis for further development / materials design of cemented carbides and particle-reinforced composite materials. Graphical abstract: Image, graphical abstract