Reactive processing of poly(lactic acid)/poly(ethylene octene) blend film with tailored interfacial intermolecular entanglement and toughening mechanism. (30th January 2022)

• Record Type: Journal Article
• Authors: He, Wenjun; Ye, Lin; Coates, Phil; Caton-Rose, Fin; Zhao, Xiaowen
• Is Part Of: Journal of materials science & technology. Volume 98(2022)
• Page Start: 186
• Page End: 196
• Publication Date: 2022-01-30
• Subjects: Poly (lactic acid)/poly (ethylene octene) (PLA/POE) blend film -- Reactive processing -- Tailored interfacial intermolecular interaction -- Long-chain branched structure -- Toughening mechanism; Metals -- Periodicals; Materials science -- Periodicals; Materials science; Metals; Periodicals; 620.1105
• DOI: 10.1016/j.jmst.2021.04.051
• Languages: English
• ISSNs: 1005-0302

Abstract

Highlights: Tailored interfacial entanglement in PLA/POE was constructed via reactive blending. POE domains were embedded tightly in PLA with abundant interface transition area. Due to enhanced molecular entanglement, PLA/POE showed strain-hardening behavior. Uniform and effectively toughened PLA/POE films with low POE content were prepared. Impact fractured surface shows plastic deformation and less interfacial de-bonding. Abstract: In order to obtain a uniform and effectively toughened poly (lactic acid) film by blending with low content of poly (ethylene octene) (POE) with high elasticity, the tailored interfacial intermolecular interaction and entanglement between the two phases of the PLA/POE blend was innovatively constructed via the facile reactive melt blending process through the reaction of the epoxy/anhydride groups grafted on the POE chains with the end groups of PLA chains (PLA/GPOE-MPOE). It was observed that POE domains were embedded tightly in PLA matrix with a fuzzy interface and abundant interface transition area, and the impact fractured surface of the blend showed an obvious plastic deformation with less occurrence of fibrillation of PLA matrix or interfacial de-bonding. Compared with neat PLA and directly blended PLA/POE blends, the PLA/GPOE-MPOE blend exhibited much higher complex viscosity/storage modulus, much lower tan δ values in the terminal region, and obvious strain-hardening behavior. The deviation in viscoelastic behavior of PLA/GPOE-MPOE from linear PLA indicated the enhanced molecular entanglement between the long-branched chains, resulting in an enhancement of the stretching ability during biaxial drawing of the blend. Uniform PLA/GPOE-MPOE films with draw ratio as high as 7 × 7 were obtained through biaxial stretching, which showed much higher tensile strength and the elongation at break than that of neat PLA and PLA/POE film. This work provides a facile method for fabricating toughening PLA films with application potentials. Graphical abstract: Image, graphical abstract