The relationship between basic group resonance and quantum yield of high efficiency red light fluorescent solutions. Issue 62 (8th December 2021)

• Record Type: Journal Article
• Authors: Lin, Yi-Shan; Tsai, Han-Yu; Huang, Jung-Kuan; Lin, Ching-Fuh
• Is Part Of: RSC advances. Volume 11:Issue 62(2021)
• Page Start: 39142
• Page End: 39146
• Publication Date: 2021-12-08
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d1ra06326j
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : The fluorescent solution with a resonance displacement of only 12.8 (cm −1 ) for the CN functional group gives this film a quantum yield as high as 84.8%. Abstract : Compared with rare earth elements and heavy metal elements, rare-earth-element-free fluorescent films can greatly reduce environmental hazards. In this study, we use a solution method to produce the fluorescent films. The film thickness is 10 μm, which can maintain fluorescent light intensity in an environment with an average humidity of 55.1 (RH%) after encapsulation. We also find that the type of solvent affects the resonance position of the CN functional group in DCJTB at a wavenumber of 2196 (cm −1 ), measured with Fourier transform infrared spectroscopy. The functional group is affected by the polar effect with its displacement decreasing with the quantum yield. Finally, we successfully made a fluorescent solution with a resonance displacement of only 12.8 (cm −1 ) for the CN functional group with the quantum yield being as high as 81.3% and a fluorescent film with a quantum yield as high as 84.8%.