Evaluation of the SEBS copolymer in the compatibility of PP/ABS blends through mechanical, thermal, thermomechanical properties, and morphology. (7th September 2021)

• Record Type: Journal Article
• Authors: Luna, Carlos Bruno Barreto; Siqueira, Danilo Diniz; Araújo, Edcleide Maria; do Nascimento, Emanuel Pereira; da Costa Agra de Melo, João Baptista
• Is Part Of: Polymers for advanced technologies. Volume 33:Number 1(2022)
• Page Start: 111
• Page End: 124
• Publication Date: 2021-09-07
• Subjects: ABS -- compatibilizer -- polymer blends -- polypropylene -- properties; Polymers -- Periodicals; 668.9
• DOI: 10.1002/pat.5495
• Languages: English
• ISSNs: 1042-7147

Abstract

Abstract: Polypropylene (PP) blends with acrylonitrile‐butadiene‐styrene (ABS) were prepared using the styrene‐ethylene‐butylene‐styrene copolymer (SEBS) as a compatibilizing agent. The blends were prepared in a co‐rotational twin‐screw extruder and injection molded. Torque rheometry, Izod impact strength, tensile strength, heat deflection temperature (HDT), differential scanning calorimetry, thermogravimetry, and scanning electron microscopy properties were investigated. The results showed that there was an increase in the torque of PA6/ABS blends with SEBS addition. The PP/ABS/SEBS (60/25/15%) blend showed significant improvement in impact strength, elongation at break, thermal stability, and HDT compared with neat PP. The elastic modulus and tensile strength have not been significantly reduced. The degree of crystallinity and the crystalline melting temperature increased, indicating a nucleating effect of ABS. The PP/ABS blends compatibilized with 12.5% and 15% SEBS presented morphology with well‐distributed fine ABS particles with good interfacial adhesion. As a result, thermal stability has been improved over pure PP and the mechanical properties have been increased, especially impact strength. In general, the addition of the SEBS copolymer as the PP/ABS blend compatibilizer has the advantage of refining the blend's morphology, increasing its toughness and thermal stability, without jeopardizing other PP properties.