Adsorption of anionic surfactant in graphite oxide: A study for treatment of laundry wastewater. Issue 6 (December 2021)

• Record Type: Journal Article
• Authors: Corona, Rayane R.B.; Sad, Cristina M.S.; da Silva, Mayara; Lopes, Diulliany L.; Leite, Juliéte S.D.; de F. Viegas, Glória M.; Gonçalves, Gustavo R.; Filgueiras, Paulo R.; de Castro, Eustáquio V.R.
• Is Part Of: Journal of environmental chemical engineering. Volume 9:Issue 6(2021)
• Publication Date: 2021-12
• Subjects: Wastewater treatment -- Anionic surfactant -- Adsorption -- Graphite oxide; Chemical engineering -- Environmental aspects -- Periodicals; Environmental engineering -- Periodicals; Chemical engineering -- Environmental aspects; Environmental engineering; Periodicals; 660.0286
• DOI: 10.1016/j.jece.2021.106858
• Languages: English
• ISSNs: 2213-2929

Abstract

Abstract: Laundry wastewater, when discharged directly into water bodies, is an environmental problem due to the high load of pollutants it contains particularly surfactant compounds that are difficult to treat by conventional processes. In this work, we evaluated the behavior of graphite oxide (GO) synthesized by the Hummer method for adsorption retention of such surfactant compounds. The adsorbent material used was graphite oxide prepared with recycled graphite from lithium batteries. The applicability of graphite oxide in the adsorption of anionic surfactant was evaluated by adsorption kinetics and physicochemical characterization, before and after adsorption, using sensitive techniques such as XRD, SEM, AFM, Raman spectroscopy and MIR-FTIR. The results showed that the adsorption kinetics well represented by the pseudo-second-order model indicating chemical interactions between surfactants and graphite oxide, with q e, calc (238.09 mg g −1 ) close to q e, exp (227.96 mg g −1 ), suggesting that pre-filtering decreases competition for adsorption sites. This result is promising for the treatment of anionic surfactants, which are the main pollutants in laundry wastewater. Graphical Abstract: ga1 Highlights: SEM-EDS showed adsorption of laundry wastewater compounds on graphite oxide surface. Raman spectra identified which substances were adsorbed on graphite oxide. Adsorption was well represented by the pseudo-second order kinetic model.