Controlled preparation of a cd(II) coordination polymer via green sonochemical synthesis: new precursors for the preparation of cadmium(II) oxide. Issue 15 (17th December 2021)

• Record Type: Journal Article
• Authors: Souri, Bagher; Abbasi, Soheila; Hayati, Payam; Farsadrooh, Majid; Rezvani, Ali Reza; Centore, Roberto
• Is Part Of: Journal of coordination chemistry. Volume 74:Issue 15(2021)
• Page Start: 2606
• Page End: 2616
• Publication Date: 2021-12-17
• Subjects: Coordination polymer -- sonochemical method -- morphology -- microstructure; Coordination compounds -- Periodicals; 541.2242
• DOI: 10.1080/00958972.2021.1981301
• Languages: English
• ISSNs: 0095-8972

Abstract

Abstract: A 2 D cadmium(II) coordination polymer (CP), [Cd(N3 )(L)]n (1 ) [L = picolinato] was synthesized by the branch tube method. Nano and microstructures of 1 were synthesized by sonochemical technique in various conditions (different times and solvents) and were identified by elemental analysis, FT-IR spectra, scanning electron microscopy (SEM), and powder X-ray diffraction (PXRD). The effects of time of reaction and solvent on the size and morphology of the nano and microstructures of 1 were also evaluated. The results showed that change in solvent leads to changes in the morphology of structures, while the change in reaction time was effective on the size of the structures. Therefore, the morphology of 1 is solvent-dependent. Graphical Abstract: UF0001