Cage-incorporation of secondary amine in Ruddlesden–Popper 2D hybrid perovskite with strong photoconductivity and polarization response. Issue 48 (25th November 2021)

• Record Type: Journal Article
• Authors: Wang, Beibei; Chen, Huaixi; Guo, Wuqian; Liu, Yi; Han, Shiguo; Hua, Lina; Tang, Liwei; Luo, Junhua; Sun, Zhihua
• Is Part Of: Journal of materials chemistry. Volume 9:Issue 48(2021)
• Page Start: 17349
• Page End: 17356
• Publication Date: 2021-11-25
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d1tc05064h
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Through the mixed-cation alloying strategy, we have successfully introduced secondary DMA + cations in perovskite cages to design a new 2D Ruddlesden–Popper hybrid perovskite, showing great potential in photodetection and polarization detection. Abstract : Two-dimensional (2D) Ruddlesden–Popper hybrid perovskites (RPHPs) have shown enormous potential for photoelectric applications owing to their advantages of structural diversity and unique physical properties. Despite extensive studies, the cage-incorporation of secondary amines ( e.g., dimethylamine, DMA) to explore 2D RPHPs remains a great challenge. Herein, we present a new member of 2D RPHPs, (BA)2 (DMA)Pb2 Br7 (1, BA + = n -butylammonium), for which organic DMA + cations are enclosed in perovskite cavities. The inorganic perovskite sheets and organic BA + spacing layers are arranged in the alternate packings, resembling a 2D quantum-well motif. This feature is advantageous for the photoconductivity properties. Consequently, the crystal-based array detectors of 1 exhibit strong photodetection performances, including high detectivity (2.0 × 10 11 Jones), large responsivity (31.1 mA W −1 ), and fast response time (∼8 μs). Moreover, its intrinsic 2D quantum-well structure endows significant anisotropy of conductivity and optical absorption, which account for the strong polarization response with a large dichroic ratio of ∼1.43, falling in the range of other 2D RPHPs. These results reveal the potential of 1 for photodetection and simultaneously shed light on the research on new candidates of 2D RPHPs.