Efficient preparation of carbon nanospheres-anchored porous carbon materials and the investigation on pretreatment methods. (January 2022)

• Record Type: Journal Article
• Authors: Huang, Ruiyi; Liu, Xiaohao; Qi, Fenglei; Jia, Liangyuan; Xu, Dongzhen; Wang, Lu; Ma, Peiyong
• Is Part Of: Bioresource technology. Volume 344:Part B(2022)
• Publication Date: 2022-01
• Subjects: Carbon nanospheres -- Fast activation -- H3PO4 hydrothermal pretreatment -- Pollutants adsorption; Biomass -- Periodicals; Biomass energy -- Periodicals; Bioremediation -- Periodicals; Agricultural wastes -- Periodicals; Factory and trade waste -- Periodicals; Organic wastes -- Periodicals; Bioénergie -- Périodiques; Déchets agricoles -- Périodiques; Déchets industriels -- Périodiques; Déchets organiques -- Périodiques; Déchets (Combustible) -- Périodiques; 662.88
• DOI: 10.1016/j.biortech.2021.126235
• Languages: English
• ISSNs: 0960-8524

Abstract

Graphical abstract: Highlights: A carbon nanospheres-anchored porous carbon material was prepared from sawdust. 1980 m 2 /g SSA was obtained in a very short activation time at 450 °C. H3 PO4 hydrothermal pretreatment is essential for material properties. The prepared material showed good adsorption performance for various pollutants. Abstract: Manufacturing high-performance activated carbon (AC) materials from abundant biomass at low temperature and short activation time is targeted by the green and sustainable chemical industry. Here, a 1980 m 2 /g of carbon nanospheres-anchored porous carbon material (PHAC) derived from waste sawdust was prepared by a method of H3 PO4 hydrothermal combined with fast activation at 450 °C within 2.8 min. It is found that H3 PO4 hydrothermal pretreatment could promote the dehydration of carbohydrates to form more unstable C = O structures, which were decomposed in the subsequent fast activation to form pore structures. In addition, this process is also conducive to the formation of carbon nanospheres, increasing the degree of graphitization and producing more graphite defects. The prepared PHAC showed good adsorption performance for different types of pollutants. This work provides a new insight for the preparation of high performance biomass based carbon materials under mild conditions.