Water Splitting by C60‐Supported Vanadium Single Atoms. Issue 52 (10th November 2021)

• Record Type: Journal Article
• Authors: Hou, Gao‐Lei; Yang, Tao; Li, Mengyang; Vanbuel, Jan; Lushchikova, Olga V.; Ferrari, Piero; Bakker, Joost M.; Janssens, Ewald
• Is Part Of: Angewandte Chemie international edition. Volume 60:Issue 52(2021)
• Page Start: 27095
• Page End: 27101
• Publication Date: 2021-11-10
• Subjects: C60 -- metal–support interaction -- single atom catalysis -- single vanadium -- water splitting; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.202112398
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Water splitting is an important source of hydrogen, a promising future carrier for clean and renewable energy. A detailed understanding of the mechanisms of water splitting, catalyzed by supported metal atoms or nanoparticles, is essential to improve the design of efficient catalysts. Here, we report an infrared spectroscopic study of such a water splitting process, assisted by a C60 supported vanadium atom, C60 V + +H2 O→C60 VO + +H2 . We probe both the entrance channel complex C60 V + (H2 O) and the end product C60 VO +, and observe the formation of H2 as a result from resonant infrared absorption. Density functional theory calculations exploring the detailed reaction pathway reveal that a quintet‐to‐triplet spin crossing facilitates the water splitting reaction by C60 ‐supported V +, whereas this reaction is kinetically hindered on the isolated V + ion by a high energy barrier. The C60 support has an important role in lowering the reaction barrier with more than 70 kJ mol −1 due to a large orbital overlap of one water hydrogen atom with one carbon atom of the C60 support. This fundamental insight in the water splitting reaction by a C60 ‐supported single vanadium atom showcases the importance of supports in single atom catalysts by modifying the reaction potential energy surface. Abstract : Splitting of water by a single vanadium is greatly facilitated by a C60 support, which can be regarded as a small piece of porous carbon nanomaterials, especially those with intrinsic pentagonal defects and curvatures. The compelling experimental and theoretical evidence demonstrates the important role of support in single vanadium atom catalysis.