New fluorinated polyimides based on 1, 2-bis(4-aminophenyl)-4, 5-bis(4-trifluoromethylphenyl)-1H-imidazole. (May 2022) - Chen, Wen-Yue
A new aromatic unsymmetrical diamine containing imidazolyl and trifluoromethyl groups, 1, 2-bis(4-aminophenyl)-4, 5-bis(4-trifluoromethylphenyl)-1H-imidazole was synthesized. A series of novel fluorinated polyimides (PIs) were prepared by polycondensation of this diamine monomer with various aromatic dianhydrides via one-step process. The resulting PIs bearing inherent viscosities of 0.45–0.61 dL/g were amorphous and readily soluble in organic polar solvents such as NMP, DMF, DMAc, THF, and CHCl3 . These new PIs exhibited good thermal stability with 10% weight loss temperatures of 530–560°C and char yields of 61–65% at 800°C in nitrogen, as well as good flame retardancy with limited oxygen index value of 40.6–42.8, and outstanding hydrophobicity with the contact angle of 85.2–93.5°. Meanwhile, all the obtained PIs exhibited low water uptake of 0.30–0.53%, strong UV-vis absorption in the range of 267–310 nm in DMF solution, and their films presented high optical transparency with a cut-off wavelength in the 355–392 nm range. Except for the PI film derived from pyromellitic dianhydride, the other PI films had the tensile strength in the range of 53.2–74.1 MPa, elongation at breakage of 6–15%, and tensile modulus of 1.0–1.5 GPa, respectively.