Ultra-Stable Lithium-Sulfur Batteries Using Nickel Phosphide@Carbon Fabric Interlayer. Issue 12 (6th December 2021)

• Record Type: Journal Article
• Authors: Yang, Kyeong Min; Kim, Soochan; Yang, Kaiwei; choi, Sungsik; Cho, Misuk; Lee, Youngkwan
• Is Part Of: Journal of the Electrochemical Society. Volume 168:Issue 12(2021)
• Publication Date: 2021-12-06
• Subjects: Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/1945-7111/ac3c25
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : Lithium-sulfur batteries (LSB) are highly promising candidates for next generation energy storage devices due to their high theoretical capacity and the low cost of sulfur. However, dissolution of lithium polysulfides (LPS) into electrolyte causes undesirable effects, resulting in loss of active materials, low Coulombic efficiency, and fast capacity fading. To address these issues, designed interlayers are inserted between a separator and S cathode to evaluate the effect of blocking of long chain LPS and catalytic conversion of LPS to Li2 S2 /Li2 S on battery performance. In order to amplify the effect of interlayer, the Ni2 P nanoparticles are electrochemically deposited on carbon fabric (CF) which exhibit excellent adsorption and conversion effect of LPS. A cell fabricated with the Ni2 P@CF interlayer allows remarkable improvement in the capacity decay of 0.04% per cycle at 1C for 1000 cycles and outstanding high rate capability. The cell delivered a capacity retention of 64% employing a current density of 8 C.