Ether‐Based Electrolyte Chemistry Towards High‐Voltage and Long‐Life Na‐Ion Full Batteries. Issue 51 (15th November 2021)

• Record Type: Journal Article
• Authors: Liang, Hao‐Jie; Gu, Zhen‐Yi; Zhao, Xin‐Xin; Guo, Jin‐Zhi; Yang, Jia‐Lin; Li, Wen‐Hao; Li, Bao; Liu, Zhi‐Ming; Li, Wen‐Liang; Wu, Xing‐Long
• Is Part Of: Angewandte Chemie international edition. Volume 60:Issue 51(2021)
• Page Start: 26837
• Page End: 26846
• Publication Date: 2021-11-15
• Subjects: ether-based electrolyte -- full cells -- high voltage -- long cycle life -- Na-ion batteries; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.202112550
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Although ether‐based electrolytes have been extensively applied in anode evaluation of batteries, anodic instability arising from solvent oxidability is always a tremendous obstacle to matching with high‐voltage cathodes. Herein, by rational design for solvation configuration, the fully coordinated ether‐based electrolyte with strong resistance against oxidation is reported, which remains anodically stable with high‐voltage Na3 V2 (PO4 )2 O2 F (NVPF) cathode under 4.5 V (versus Na + /Na) protected by an effective interphase. The assembled graphite//NVPF full cells display superior rate performance and unprecedented cycling stability. Beyond that, the constructed full cells coupling the high‐voltage NVPF cathode with hard carbon anode exhibit outstanding electrochemical performances in terms of high average output voltage up to 3.72 V, long‐term cycle life (such as 95 % capacity retention after 700 cycles) and high energy density (247 Wh kg −1 ). In short, the optimized ether‐based electrolyte enriches systematic options, the ability to maintain oxidative stability and compatibility with various anodes, exhibiting attractive prospects for application. Abstract : By rational design of the solvation configuration, a cation–solvent fully coordinated ether‐based electrolyte with strong oxidation resistance up to 4.5 V (versus Na + /Na) was developed and applied in graphite//NVPF and LHC//NVPF full cells which showed superior rate performance and unprecedented cycling stability.