Nematic shells: new insights in topology- and curvature-induced effects. Issue 45 (4th November 2021)

• Record Type: Journal Article
• Authors: Napoli, Gaetano; Pylypovskyi, Oleksandr V.; Sheka, Denis D.; Vergori, Luigi
• Is Part Of: Soft matter. Volume 17:Issue 45(2021)
• Page Start: 10322
• Page End: 10333
• Publication Date: 2021-11-04
• Subjects: Soft condensed matter -- Periodicals; 530.413
• DOI: 10.1039/d1sm00719j
• Languages: English
• ISSNs: 1744-683X

Abstract

Abstract : We propose a model for nematic shells where out-of-tangent-plane escapes of the director field are allowed. This uplift triggers a novel effect: curvature-induced chirality. We also study the effect of curvature on the textures of a spherical shell. Abstract : Within the framework of continuum theory, we draw a parallel between ferromagnetic materials and nematic liquid crystals confined on curved surfaces, which are both characterized by local interaction and anchoring potentials. We show that the extrinsic curvature of the shell combined with the out-of-plane component of the director field gives rise to chirality effects. This interplay produces an effective energy term reminiscent of the chiral term in cholesteric liquid crystals, with the curvature tensor acting as a sort of anisotropic helicity. We discuss also how the different nature of the order parameter, a vector in ferromagnets and a tensor in nematics, yields different textures on surfaces with the same topology as the sphere. In particular, we show that the extrinsic curvature governs the ground state configuration on a nematic spherical shell, favouring two antipodal disclinations of charge +1 on small particles and four +1/2 disclinations of charge located at the vertices of a square inscribed in a great circle on larger particles.