Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof. Issue 53 (11th October 2021)
- Record Type:
- Journal Article
- Title:
- Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof. Issue 53 (11th October 2021)
- Main Title:
- Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof
- Authors:
- Madroñero, Diego
Mujica-Martinez, Cesar A.
Vázquez, Alfredo - Abstract:
- Abstract : A cascade process to construct synthetically valuable β-keto-β′-acylcycloalkanecarboxylic acid esters and their transformation into bicyclic and tricyclic systems through intramolecular condensation reactions. Abstract : Lithium anions derived from O-carbonate-protected cyanohydrins undergo conjugate addition to cycloalkenones with the concomitant transfer of the alkoxycarbonyl group to produce tricarbonyl compounds. These products offer numerous possibilities for further elaboration. The synthetic potential of the cascade products was demonstrated by forming bicyclic and tricyclic systems through intramolecular condensation reactions.
- Is Part Of:
- RSC advances. Volume 11:Issue 53(2021)
- Journal:
- RSC advances
- Issue:
- Volume 11:Issue 53(2021)
- Issue Display:
- Volume 11, Issue 53 (2021)
- Year:
- 2021
- Volume:
- 11
- Issue:
- 53
- Issue Sort Value:
- 2021-0011-0053-0000
- Page Start:
- 33235
- Page End:
- 33244
- Publication Date:
- 2021-10-11
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/RA ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d1ra05187c ↗
- Languages:
- English
- ISSNs:
- 2046-2069
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8036.750300
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 19946.xml