DIBALH: from known fundamental to an unusual reaction; chemoselective partial reduction of tertiary amides in the presence of esters. Issue 53 (18th October 2021)
- Record Type:
- Journal Article
- Title:
- DIBALH: from known fundamental to an unusual reaction; chemoselective partial reduction of tertiary amides in the presence of esters. Issue 53 (18th October 2021)
- Main Title:
- DIBALH: from known fundamental to an unusual reaction; chemoselective partial reduction of tertiary amides in the presence of esters
- Authors:
- Heo, Yu Jin
Kim, Hyun Tae
Jaladi, Ashok Kumar
An, Duk Keun - Abstract:
- Abstract : Highly chemoselective partial reduction of tertiary amides to aldehydes over esters are reported with commercial DIBALH. Various aldehydes are synthesized in excellent yields. Abstract : This study presents a quick and reliable approach to the chemoselective partial reduction of tertiary amides to aldehydes in the presence of readily reducible ester groups using commercial DIBALH reagent. Moreover, the developed method was also extended to multi-functional molecules bearing ester moieties, which were successfully chemoselectively reduced to the corresponding aldehydes.
- Is Part Of:
- RSC advances. Volume 11:Issue 53(2021)
- Journal:
- RSC advances
- Issue:
- Volume 11:Issue 53(2021)
- Issue Display:
- Volume 11, Issue 53 (2021)
- Year:
- 2021
- Volume:
- 11
- Issue:
- 53
- Issue Sort Value:
- 2021-0011-0053-0000
- Page Start:
- 33809
- Page End:
- 33813
- Publication Date:
- 2021-10-18
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/RA ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d1ra06279d ↗
- Languages:
- English
- ISSNs:
- 2046-2069
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8036.750300
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 19946.xml