A new metal–organic framework based on rare [Zn4F4] cores for efficient separation of C2H2. Issue 95 (16th November 2021)

• Record Type: Journal Article
• Authors: Shi, Wen-Juan; Li, Yong-Zhi; Chen, Jing; Su, Run-Han; Hou, Lei; Wang, Yao-Yu; Zhu, Zhonghua
• Is Part Of: Chemical communications. Volume 57:Issue 95(2021)
• Page Start: 12788
• Page End: 12791
• Publication Date: 2021-11-16
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d1cc05196b
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Assembly via 1, 4-benzenedicarboxylate linker and Zn 2+ ions afforded a new MOF containing novel [Zn4 F4 ] cubane cores, showing excellent C2 H2 separation from C2 H2 –CO2 and C2 H2 –CH4 mixtures. Abstract : Assembly via 1, 4-benzenedicarboxylate linkers and Zn 2+ ions afforded an MOF containing rare [Zn4 F4 ] cubane core, showing excellent separation for C2 H2 –CO2 and C2 H2 –CH4 mixtures. Dynamic breakthrough experiments and grand canonical Monte Carlo calculations were carried out to confirm the feasibility of the MOF for the separation application of C2 H2 .