Synthesis and antioxidant properties of a novel arylamine antioxidant. (30th August 2021)

• Record Type: Journal Article
• Authors: Chao, Mianran; Fan, Rong; Zhang, Lulu; Wang, Xiaoyu; Shu, Qianhui; Gao, Jifeng; Chen, Lele; Gong, Peiwei; Shen, Duyi
• Is Part Of: Bulletin of the Korean Chemical Society. Volume 42:Number 11(2021)
• Page Start: 1440
• Page End: 1445
• Publication Date: 2021-08-30
• Subjects: antioxidant -- ester oil -- lubricant -- oxidation stability -- synergism; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/bkcs.12384
• Languages: English
• ISSNs: 0253-2964

Abstract

Abstract: A novel oil‐soluble arylamine antioxidant N 1, N 2 ‐diphenylethane‐1, 2‐diamine (ND) was successfully synthesized, and the potential antioxidant behavior of which had never been reported before. The structure of ND was characterized via nuclear magnetic resonance ( 1 H NMR, 13 C NMR) and electron ionization mass spectrometry. The antioxidant performance of ND and its synergistic effect with 2, 6‐di‐tert‐butyl‐4‐methylphenol (BHT) in di‐2‐ethylhexyl sebacate were evaluated by pressurized differential scanning calorimetry, thermogravimetry analysis, and hot oil oxidation test. All the results indicated that the synthesized antioxidant ND exhibited outstanding antioxidant performance and showed prominent synergistic effect with BHT in ester base oil. Furthermore, the probable synergistic anti‐oxidative effect between ND and BHT was discussed, which was mainly induced by the formation of a fresh BHT radical and the regeneration of ND antioxidant. Abstract : A novel oil‐soluble arylamine antioxidant N 1, N 2 ‐diphenylethane‐1, 2‐diamine (ND) was successfully synthesized and its potential antioxidant behavior was firstly studied. The results demonstrated that ND exhibited outstanding antioxidant performance and prominent synergistic effect with 2, 6‐di‐tert‐butyl‐4‐methylphenol (BHT) in lubricant oil.