Electrochemical Synthesis of Selenium‐substituted Benzoxazine via Radical Initiated Cyclization. Issue 21 (15th October 2021)

• Record Type: Journal Article
• Authors: Lin, Xinxin; Zeng, Cuilian; Pang, Xinyan; Zhu, Chenlong; Liu, Chengkou; Yang, Xiaobing; Hu, Yujing; Fang, Zheng; Guo, Kai
• Is Part Of: ChemElectroChem. Volume 8:Issue 21(2021)
• Page Start: 4091
• Page End: 4095
• Publication Date: 2021-10-15
• Subjects: electrochemical synthesis -- benzoxazine -- cyclization -- metal free -- free radicals; Electrochemistry -- Periodicals; 541.37
• DOI: 10.1002/celc.202101013
• Languages: English
• ISSNs: 2196-0216

Abstract

Abstract: A strategy for electrochemically synthesizing selenium benzoxazines through o ‐vinylaniline and diselenide has been developed. This metal‐free and oxidant‐free electrochemical synthesis method is carried out in an undivided cell under mild conditions, which is more environmentally friendly. Moreover, a variety of selenium‐substituted benzoxazine can be prepared in good yield with a broad scope and functional group tolerance, which has potential industrial application value. Abstract : A metal‐free and oxidant‐free green strategy for the electrochemical synthesis of benzoxazine selenium by o ‐vinylaniline and diselenide is reported.