A longevity study to determine appropriate storage conditions for sexual lubricants using spectroscopic and spectrometric techniques. (November 2021)

• Record Type: Journal Article
• Authors: Baumgarten, Brooke; Thomas, Santana; Flynn, Nancy; Marić, Mark; Bridge, Candice
• Is Part Of: Forensic science international. Volume 328(2021)
• Publication Date: 2021-11
• Subjects: Medical jurisprudence -- Periodicals; Chemistry, Forensic -- Periodicals; Forensic Medicine -- Periodicals; Médecine légale -- Périodiques; Chimie légale -- Périodiques; Gerechtelijke geneeskunde; Gerechtelijke chemie; Gerechtelijke psychiatrie; Chemistry, Forensic; Medical jurisprudence; Electronic journals; Periodicals; Electronic journals; 614.1
• DOI: 10.1016/j.forsciint.2021.111036
• Languages: English
• ISSNs: 0379-0738

Abstract

Abstract: There has been an increase in the number of reported cases in which assailants have used a condom or sexual lubricant. Sexual predators understand that DNA from seminal fluid is one of the main forms of evidence used to connect a suspect to a victim or crime scene; therefore, the use of condoms in sexual assault cases has increased. This dilemma has led to research into other types of trace evidence (e.g., sexual lubricants). The study presented herein was performed to determine the optimal storage time length and conditions appropriate for storing trace lubricant residue. This research project used Fourier transform infrared spectroscopy (FTIR), direct analysis in real time-high resolution mass spectrometry (DART-HRMS), and gas chromatography-mass spectrometry (GC-MS) techniques to analyze the stored swabs containing sexual lubricants at 8 timepoints over 18 months. Blank, personal lubricant, and condom swabs were stored under several environmental conditions. Swab storage allowed for the determination of whether lubricants degraded, thus adversely affecting the ability to recognize the classification patterns. Resulting spectra from each instrument can be used to identify environmental degradation of lubricant samples and generate investigative leads. Pearson Correlation Coefficients and time plots of the chemical components were used to determine if chemical breakdown occurred for each lubricant and if the pattern changed significantly. Results showed that the strongest correlations occur between the initial timepoint (T 0) and one month (T1 m ), with correlations decreasing consistently up to eighteen months (T18 m ). The best storage conditions were determined to be 22 °C at both 16% and 50% humidity. The ability to understand the effects of environment and time to the analysis of sexual lubricants may offer helpful information when analyzing sexual assault kits. Graphical Abstract: ga1 Highlights: Sexual lubricant residues may be stored for months before forensic analysis. Samples stored under various conditions to determine how chemical profiles change. Samples analyzed using GC-MS, FT-IR and DART-HRMS. The optimal storage condition was at room temperature with low to medium humidity.