A novel intrinsic semi-aromatic polyamide dielectric toward excellent thermal stability, mechanical robustness and dielectric performance. (8th November 2021)

• Record Type: Journal Article
• Authors: Ning, Jingyi; Tian, Chong; Yang, Yunyun; Huang, Lei; Lv, Jiahao; Zeng, Fanhao; Liu, Qiang; Zhao, Fuqi; Kong, Weibo; Cai, Xufu
• Is Part Of: Polymer. Volume 234(2021)
• Publication Date: 2021-11-08
• Subjects: Dielectric polymers -- Semi aromatic polyamides -- Toughness -- Breakdown strength; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.polymer.2021.124233
• Languages: English
• ISSNs: 0032-3861

Abstract

Abstract: The development of aliphatic polyamide as dielectric polymer is limited due to relatively high dielectric loss, low breakdown strength and low servicing temperature. Different from the traditional ways for enhancing the dielectric properties of aliphatic polyamides by compositing with inorganic materials, here an alternative strategy is reported via random copolymerizing aliphatic polyamide with semi aromatic polyamides as functional segments. The designed co-polyamide shows decreased dielectric loss of 0.04 and enhanced breakdown strength of 319 MV/m with a low content of semi aromatic polyamides. Moreover, taking advantage of the inherent rigid benzene ring and flexible aliphatic chain, high glass transition temperature and great toughness are achieved simultaneously in the prepared semi aromatic polyamides. The introduction of aromatic segments has also improved dielectric and mechanical properties of co-polyamide at elevated temperature (150 °C), which is desirable and crucial for polymer dielectrics. The strategy provides new possibilities for the development of high-performance intrinsic polymer dielectrics. Graphical abstract: Image 1 Highlights: A facile method was used to synthesize a novel linear Co–PAs by PA 911 and PA 10T. Co–PAs can achieve relatively high dielectric constant, breakdown strength and reduced dielectric loss. Co–PAs have excellent mechanic toughness, even under high temperature.