Facile synthesis of air-stable heterobimetallic osmium-silver hydride complexes. Issue 35 (1st September 2021)

• Record Type: Journal Article
• Authors: Zhou, Haiyu; Bai, Tongtong; Pan, Yanlin; Wei, Yongliang; Wang, Tongdao
• Is Part Of: Dalton transactions. Volume 50:Issue 35(2021)
• Page Start: 12093
• Page End: 12097
• Publication Date: 2021-09-01
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d1dt02619d
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : We have presented highly efficient approaches for the construction of neutral and air-stable heterobimetallic Os–Ag hydride complexes. Abstract : The synthesis and characterization of air-stable heterobimetallic Os–Ag hydrides are described. All of the new heterobimetallic Os–Ag hydrides are neutral, and the in situ generated and presynthesized cis -[Os](H)–CC–R units in these frameworks act as organometallic bidentate chelating ligands coordinating with the AgPPh3 cation, which makes these complexes more stable. Our results provide a new synthetic route for the construction of stable heterobimetallic complexes.