Photocatalytic intermolecular carboarylation of alkenes by selective C–O bond cleavage of diarylethers. Issue 73 (20th August 2021)

• Record Type: Journal Article
• Authors: Ji, Meishan; Chang, Chenyang; Wu, Xinxin; Zhu, Chen
• Is Part Of: Chemical communications. Volume 57:Issue 73(2021)
• Page Start: 9240
• Page End: 9243
• Publication Date: 2021-08-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d1cc04038c
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Disclosed herein is a novel radical-mediated intermolecular carboarylation of alkenes by cleaving inert C–O bonds. Abstract : Disclosed herein is a novel radical-mediated intermolecular carboarylation of alkenes by cleaving inert C–O bonds. The strategically designed arylbenzothiazolylether diazonium salts are harnessed as dual-function reagents. A vast array of alkenes are proven to be suitable substrates. The benzothiazolyl moiety in the products serves as the formyl precursor, and the OH residue provides the cross-coupling site for further product elaboration, indicating the robust transformability of the products.