An air-stable n-type bay-and-headland substituted bis-cyano N–H functionalized perylene diimide for printed electronics. Issue 39 (30th September 2021)

• Record Type: Journal Article
• Authors: Park, Irene E.; Brixi, Samantha; Martell, Mark; Ocheje, Michael U.; Pettipas, Richard D.; Harris, Dylan H.; Gelfand, Benjamin S.; Rondeau-Gagné, Simon; Lessard, Benoit H.; Welch, Gregory C.
• Is Part Of: Journal of materials chemistry. Volume 9:Issue 39(2021)
• Page Start: 13630
• Page End: 13634
• Publication Date: 2021-09-30
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d1tc03873g
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Design, synthesis, and characterization of an electron deficient N-H functionalized perylene diimide, with halogen-free solvent solubility, for air-stable transistor operation. Abstract : The synthesis of a 6, 11-bis-cyano N–H functionalized perylene diimide is reported. Electron withdrawing cyano groups were installed to counter the electron donating cyclic amine moiety with retention of functionality. Solution-processed, air-stable organic field-effect transistors are demonstrated using this new material.