Core level shifts as indicators of Cr chemistry on hydroxylated α-Al2O3(0001): a combined photoemission and first-principles study. Issue 38 (23rd September 2021)

• Record Type: Journal Article
• Authors: Messaykeh, Maya; Chenot, Stéphane; David, Pascal; Cabailh, Gregory; Jupille, Jacques; Koltsov, Alexey; Lagarde, Pierre; Trcera, Nicolas; Goniakowski, Jacek; Lazzari, Rémi
• Is Part Of: Physical chemistry chemical physics. Volume 23:Issue 38(2021)
• Page Start: 21852
• Page End: 21862
• Publication Date: 2021-09-23
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/d1cp03224k
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Core level photoemission combined with atomistic simulations of chemical shifts evidences a chemical reaction between Cr and residual OH groups at the Al2 O3 (000) surface. Abstract : The Cr/α-Al2 O3 (0001) interface has been explored by X-ray photoemission spectroscopy, X-ray absorption spectroscopy (XAS) and ab initio first-principles calculations of core level shifts including final state effects. After an initial oxidation via a reaction with residual surface OH but no reduction of the alumina substrate, Cr grows in a metallic form without any chemical effect on the initially oxidized Cr. However, Cr metal lacks crystallinity. Long-range (reflection high energy electron diffraction) and short-range (XAS) order are hardly observed. Thus photoemission combined with atomistic simulations becomes a unique tool to explore the chemistry and environment at the Cr/alumina interface. Cr 2p, O 1s and Al 2s shifted components are all explained by the formation of moieties involving Cr 3+ and/or Cr 4+ and of metallic Cr 0, which supports the previously found Cr buffer mechanism for poorly adhesive metals. Beyond the situation under study, the present data demonstrate the ability of a combined experimental and theoretical approach of core-level shifts to exhaustively describe the general case of disordered metal/oxide interfaces.