A soluble iron(ii)-phthalocyanine-catalyzed intramolecular C(sp3)–H amination with alkyl azides. Issue 82 (23rd September 2021)

• Record Type: Journal Article
• Authors: You, Tingjie; Zeng, Si-Hao; Fan, Jianqiang; Wu, Liangliang; Kang, Fangyuan; Liu, Yungen; Che, Chi-Ming
• Is Part Of: Chemical communications. Volume 57:Issue 82(2021)
• Page Start: 10711
• Page End: 10714
• Publication Date: 2021-09-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d1cc04573c
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A soluble iron(ii )-phthalocyanine, [Fe II ( t Bu4 Pc)(py)2 ], is an effective catalyst in intramolecular C(sp 3 )–H bond amination of alkyl azides to give the amination products in moderate to excellent yields with a broad substrate scope. Abstract : Herein, we describe a soluble iron(ii )-phthalocyanine, [Fe II ( t Bu4 Pc)(py)2 ] (Pc = phthalocyaninato(2–)), as an effective catalyst in intramolecular C(sp 3 )–H bond amination, with alkyl azides as the nitrogen source, to afford the amination products in moderate to excellent yields with a broad substrate scope.