Anodic substitution reaction of carbamates in a flow microreactor using a stable emulsion solution. Issue 11 (11th October 2021)

• Record Type: Journal Article
• Authors: Mikami, Rio; Nakamura, Yuto; Shida, Naoki; Atobe, Mahito
• Is Part Of: Reaction chemistry & engineering. Volume 6:Issue 11(2021)
• Page Start: 2024
• Page End: 2028
• Publication Date: 2021-10-11
• Subjects: Reaction mechanisms (Chemistry) -- Periodicals; Chemical engineering -- Periodicals; Chemical engineering; Reaction mechanisms (Chemistry); Periodicals; 547.705
• DOI: 10.1039/d1re00403d
• Languages: English
• ISSNs: 2058-9883

Abstract

Abstract : An anodic substitution reaction in a flow microreactor using a stable emulsion solution prepared by tandem acoustic emulsification is demonstrated. Abstract : An anodic substitution reaction in a flow microreactor using a stable emulsion solution prepared by tandem acoustic emulsification is demonstrated for the first time. The emulsion solution facilitated the selective anodic oxidation of carbamates, and the α-substituted products were ejected from the flow reactor to suppress overoxidation, resulting in an increase in the current efficiency for the desired reaction.