Access to adducts of parent iminoborane isomers, HBNH and NBH2, using frustrated Lewis pair chelation. Issue 83 (28th September 2021)

• Record Type: Journal Article
• Authors: Frenette, Brandon L.; Omaña, Alvaro A.; Ferguson, Michael J.; Zhou, Yuqiao; Rivard, Eric
• Is Part Of: Chemical communications. Volume 57:Issue 83(2021)
• Page Start: 10895
• Page End: 10898
• Publication Date: 2021-09-28
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d1cc04923b
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A general frustrated Lewis pair chelation approach was used to access the parent iminoborane isomers HBNH and NBH2 . Abstract : Adducts of the parent iminoborane isomers, HBNH and NBH2, have been prepared, each stabilized by the frustrated Lewis pair (FLP) chelate i Pr2 P(C6 H4 )BCy2 (PB). PB{HBNH} was accessed via dehydrohalogenation, while the corresponding isomer PB{NBH2 } was obtained from the borylation of the formal nitrene-FLP complex PB{NH} .