Ferroic phase transitions and magnetoelectric coupling in cobalt doped BaTiO3. Issue 37 (23rd August 2021)

• Record Type: Journal Article
• Authors: Pradhan, Dhiren K.; Mohanty, Hari Sankar; Kumari, Shalini; Bhoi, Krishnamayee; Tang, Nan; Ravikant, ; Rahaman, M. M.; Pradhan, Dillip K.; Kumar, Ashok; Gilbert, Dustin A.; Rack, Philip D.
• Is Part Of: Journal of materials chemistry. Volume 9:Issue 37(2021)
• Page Start: 12694
• Page End: 12711
• Publication Date: 2021-08-23
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d1tc02961d
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : The ferroelectric and magnetoelectric (ME) properties of cobalt doped BaTiO3 samples. Abstract : Magnetoelectric (ME) materials exhibit interesting physics with cross coupling between ferroelectric and magnetic order parameters and thus strong potential to be utilized in memory, spintronics and other multifunctional electronic/magnetic devices. Doping of suitable transition metals in ferroelectrics can induce magnetism and ME coupling and modify the physical properties. Here, we report the structural, electronic, magnetic and ME coupling of 3.5, 5 and 7.5 mol% cobalt doped BaTiO3 (BTO) ceramics. X-ray diffraction and Raman spectroscopy indicate that the samples are single phase having a tetragonal crystal structure with P 4 mm symmetry. The tetragonality ratio is found to decrease with increasing cobalt content. We observed a Fano-like asymmetric peak in the [ A 1 (LO1 )] Raman mode at ∼173 cm −1 in all the cobalt doped BTO samples. The cobalt dopants are shown to be uniformly distributed throughout the surface of the samples. We observed a lowering of the ferroelectric transition temperature and increasing diffusivity parameter with increasing cobalt concentration. The electrical properties of all the samples have been investigated in detail by impedance spectroscopy and ac conductivity studies before and after the ferroelectric phase transitions. All the samples show hysteretic ferroelectric behavior with a clear saturation state that decreases with increasing cobalt content. The observed ferroelectricity in these samples is intrinsic in nature. The 3.5% cobalt doped BTO sample exhibits paramagnetic behavior whereas the 5 and 7.5% cobalt doped BTO samples show ferromagnetic ordering below 43 K. The 7.5% cobalt doped BTO samples show significant ME coupling.