Natural polymer towards lustrous multicolored silk: Hermetical encapsulation and understanding of colorants via controlled de/recrystallization process. (26th October 2021)

• Record Type: Journal Article
• Authors: Win, Khin Yin; Teng, Choon Peng; Tee, Si Yin; Guan, Guijian; Loh, Xian Jun; Han, Ming-Yong
• Is Part Of: Polymer. Volume 233(2021)
• Publication Date: 2021-10-26
• Subjects: Silk fibroin -- Crystallization -- Encapsulation -- Colors -- Cosmetics -- Safety; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.polymer.2021.124163
• Languages: English
• ISSNs: 0032-3861

Abstract

Abstract: We develop an innovative approach to utilize silk, a natural polymer with discrete hydrophobic blocks interspersed with hydrophilic domains for hermetically encapsulating hydrophilic colorants to create a palette of lustrous multicolored silk while retaining its unique properties and rendering new functionalities. The success is largely dependent on the structures of colorants, the recrystallization of silk and the affinity between them. It is important to examine phase transfer capabilities and phase distribution coefficients of colorants in the presence/absence of silk, which are considered as influential factors in evaluation and selection of suitable colorants and matrices for effective encapsulation of colorants to produce safe and healthy cosmetics. As a result, this formulated silk increases color-encapsulating efficiency, prolongs color-retaining capability, enhances color physiochemical stability, reduces cytotoxicity and provides spreadability for potential use in cosmetic application. Meanwhile, it also presents flexibility to incorporate both organic and inorganic colorants together with a variety of more materials including fragrances, hydrating agents, antioxidants, UV fillers, etc. Graphical abstract: This paper reports the development of multicolor silk palette towards next-gen safe cosmetics through innovative incorporation of FDA-approved organic/inorganic dyes into natural polymer - silk fibroin by optimized and controlled de/recrystallization process. The use of expression with CIE color spaces will greatly be appreciated to achieve the most suitable colors for a given makeup task, from the mixture of different silk colors. Image 1 Highlights: Natural polymer silk towards lustrous multicolored silk. Hermetical encapsulation of colorants via controlled de/recrystallization process. Increase color retention, enhance stability and reduce cytotoxicity. Offer safe and healthy cosmetics ingredients.