Degradation study for the membrane electrode assembly of anion exchange membrane fuel cells at a single-cell level. Issue 34 (20th August 2021)

• Record Type: Journal Article
• Authors: Hyun, Jonghyun; Yang, Seok Hwan; Doo, Gisu; Choi, Sungyu; Lee, Dong-Hyun; Lee, Dong Wook; Kwen, Jiyun; Jo, Wonhee; Shin, Sang-Hun; Lee, Jang Yong; Kim, Hee-Tak
• Is Part Of: Journal of materials chemistry. Volume 9:Issue 34(2021)
• Page Start: 18546
• Page End: 18556
• Publication Date: 2021-08-20
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d1ta05801k
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : The cathode side catalyst and binder were severely deteriorated compared to the membrane and that of the anode side during the constant current operation. This is due to the high local pH of the cathode caused by the water imbalance inside the MEA. Abstract : The durability of the membrane electrode assembly (MEA) is one of the important requirements for the successful commercialization of anion exchange membrane fuel cells (AEMFCs). While chemical stabilities of the components (the catalyst, membrane, and ionomer) have been assessed by ex situ tests, the degradation mode of the components in a single-cell is still not fully understood. Herein, the degradation of a MEA based on an ionomer having a polycarbazole main chain and a trimethyl ammonium side group was systematically investigated for a single-cell level under constant current conditions. The degradations of the catalyst, membrane, and ionomer were compared by in situ electrochemical and ex situ post-mortem analyses. The catalyst and ionomer in the cathode showed significant degradation, whereas the membrane was relatively durable, suggesting that the formation of a strong alkaline environment in the cathode catalyst layer is a major cause of the performance fade. The use of an alkaline-stable ionomer with an N, N -dimethylhexylamine group, which is designed based on density functional theory (DFT) calculations, in the cathode catalyst layer leads to 87% durability improvement. This work enhances the understanding of the key factors affecting the durability of AEMFCs under real operation and suggests practical strategies toward higher durability.