Encapsulation of high specific surface area red blood cell-like mesoporous carbon spheres by magnetic nanoparticles: A new strategy to realize multiple electromagnetic wave loss mechanism. (30th October 2021)

• Record Type: Journal Article
• Authors: Wei, Bo; Zhou, Congyu; Yao, Zhengjun; Chen, Ping; Wang, Mengqing; Li, Zhejia; Zhou, Jintang; Hou, Jinsen; Li, Wan
• Is Part Of: Carbon. Volume 184(2021)
• Page Start: 232
• Page End: 244
• Publication Date: 2021-10-30
• Subjects: Red blood cell-like carbon spheres -- Mesoporous -- Microwave absorption -- Electromagnetic performance; Carbon -- Periodicals; Carbone -- Périodiques; Koolstof; Toepassingen; Electronic journals; 546.681
• DOI: 10.1016/j.carbon.2021.08.029
• Languages: English
• ISSNs: 0008-6223

Abstract

Abstract: Accompanied by the increasingly serious disordered electromagnetic radiation to trigger electromagnetic pollution become a new generation source which is harmful and difficult to protect, it is still a enormous challenge to develop a novel microwave absorbing materials (MAM) with low-density and wide absorption band. Here, we propose an advanced strategy to encapsulate red blood cell-like mesoporous carbon spheres with magnetic nanoparticles in terms of the problems of poor impedance matching, narrow absorption band of single dielectric loss material or high density of single magnetic loss material. A novel microwave absorber (MRBC), exhibited with the characteristics of ultra-high specific surface area (BET specific surface area: >500 m 2 /g), uniform mesoporous properties (Pore diameter: 7–8 nm) and special hollow structure and composed of carbon spheres with intact red blood cell morphology and magnetic nanoparticles, was obtained by the combination of double vacuum sintering processes and glycolate pyrolysis process. The unique microstructure and the synergistic effect of multiple dielectric loss and magnetic loss capability make MRBC-3 achieve an effective bandwidth of 5.77 GHz at a low filling rate (15 wt%) and an ultra-thin thickness (1.74 mm). Meanwhile, the minimum reflection loss of MRBC-4 is −64.26 dB. Furthermore, we use normalized input impedance to discuss the special properties of quarter wavelength matching layer, and verify the location of minimum reflection loss. Graphical abstract: Image 1 Highlights: MRBC maintains a complete red blood cell structure and regular mesoporous property. Magnetic particles are cleverly encapsulated in the voids and depressions of MRBC. MRBC-3 achieve an effective bandwidth of 5.77 GHz at 1.74 mm. The relationship between impedance matching and RL min is verified.