Redox‐Mediated Red‐Phosphorous Semi‐Liquid Anode Enabling Metal‐Free Rechargeable Na‐Seawater Batteries with High Energy Density. Issue 38 (1st September 2021)

• Record Type: Journal Article
• Authors: Kim, Yongil; Varzi, Alberto; Mariani, Alessandro; Kim, Guk‐Tae; Kim, Youngsik; Passerini, Stefano
• Is Part Of: Advanced energy materials. Volume 11:Issue 38(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-09-01
• Subjects: phosphorus -- polycyclic aromatic hydrocarbons -- redox mediators -- seawater batteries -- semi‐liquid anodes -- sodium; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.202102061
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract: Sodium‐seawater batteries (Na‐SWB) are considered among the most promising electrochemical devices for large‐scale energy storage and the marine sector. In fact, by employing an open‐structured cathode, they benefit from the unlimited supply of sodium from seawater. This means, that the energy of such systems is intrinsically limited by the capacity of the anode. In order to increase the energy of Na‐SWB, it is therefore necessary to introduce a high‐capacity anode such as, e.g., red phosphorus. However, due to its large volume changes upon charge/discharge processes, obtaining thick electrodes and large areal capacity is extremely challenging. Herein, the areal/absolute capacity of the red phosphorus anode is increased by employing a semi‐liquid electrode, which includes two redox mediators, i.e., sodium‐biphenyl and sodium‐pyrene, as reducing and oxidizing species for the exploitation of the full red phosphorus capacity. As a result, the red phosphorus semi‐liquid anode in Na‐SWB provides a high‐capacity of 15 mAh cm –2 in a static anode, showing great energy storage potential for operation in flow‐mode when storing the semi‐liquid negative electrode in a storage tank. Abstract : Red‐phosphorus semi‐liquid electrodes are investigated as anodes for metal‐free rechargeable Na‐seawater batteries with high energy density. The red‐phosphors semi‐liquid electrode, made by mixing P/C composite powder with a redox‐mediators‐based electrolyte solution (P/C @ Na‐BP‐PYRs), enables a high areal capacity of 26 mAh using a small coin cell. The two redox mediators act as reducing and oxidizing species for the red‐phosphorus.