Tandem Functionalization‐Carboxylation Reactions of π‐Systems with CO2. Issue 11 (22nd September 2021)

• Record Type: Journal Article
• Authors: Bertuzzi, Giulio; Cerveri, Alessandro; Lombardi, Lorenzo; Bandini, Marco
• Is Part Of: Chinese journal of chemistry. Volume 39:Issue 11(2021)
• Page Start: 3116
• Page End: 3126
• Publication Date: 2021-09-22
• Subjects: Catalysis -- Carboxylation -- CO2 -- Tandem reaction -- π‐Systems; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/cjoc.202100450
• Languages: English
• ISSNs: 1001-604X

Abstract

Abstract: The tandem catalytic functionalization/carboxylation of double as well as triple carbon‐carbon bonds with CO2 represent an emerging research area in synthetic organic methodology. In particular, the combination of mild reaction conditions, stoichiometric acceptor/donorless conditions (visible light photoredox catalysis) and chiral catalysts contributed to a rapid development of this intriguing research area capable of creating chemical diversity/ complexity from readily available unsaturated hydrocarbons and CO2 as a C1‐buinding block. The most recent developments in the field have been collected in the present review article and organized, based on the different sets of π‐systems/intermediates/reactive partners employed ( i.e., nickelalactones, organo‐halides) as well as synthetic strategies ( i.e., visible‐light photo redox catalysis). Abstract :