A new 3D 3-fold interpenetrated framework from flexible tricarboxylate: Photocatalytic and sensing performances. (15th November 2021)

• Record Type: Journal Article
• Authors: Zhou, Shanhe; Wang, Jun; Liu, Dong; Cai, Shulan; Guo, Junru; Panc, Ying; Zheng, Rouqiao; Muddassir, Mohd.; Sakiyama, Hiroshi
• Is Part Of: Polyhedron. Volume 209(2021)
• Publication Date: 2021-11-15
• Subjects: MOF -- Rh B -- Photocatalysis -- Sensor; Chemistry, Inorganic -- Periodicals; Chimie inorganique -- Périodiques; Organometaalverbindingen; Anorganische chemie; 546.05
• DOI: 10.1016/j.poly.2021.115454
• Languages: English
• ISSNs: 0277-5387

Abstract

Graphical abstract: Abstract: A new metal–organic framework of {[Zn2 (HL)2 (4, 4′-bipy)]·3H2 O}n (1 ) (H3 L = 1, 3, 5-tris(4-carbonylphenyloxy)benzene, 4, 4′-bipy = 4, 4′-bipyridine), was hydrothermally prepared and full characterized. 1 possesses 3D 3-fold interpenetrated framework. 1 obtained effectively photocatalytic performance to the disintegration of dyes Rhodamine B (Rh B) and methylene blue (MB). Furthermore, MOF 1 was selected as a selective probe for antibiotics metronidazole (MDZ) having the low detection limit 1.16 ppm. The plausible mechanism displayed by 1 for the catalytic degradation toward Rh B was proposed using the trapping method and LC-MS studies.