Hierarchical Cu(OH)2@Co(OH)2 Nanotrees for Water Oxidation Electrolysis. Issue 16 (22nd June 2020)

• Record Type: Journal Article
• Authors: Tang, Shasha; Li, Xiaogang; Courté, Marc; Peng, Jingjing; Fichou, Denis
• Is Part Of: ChemCatChem. Volume 12:Issue 16(2020)
• Page Start: 4038
• Page End: 4043
• Publication Date: 2020-06-22
• Subjects: hydroxide -- water oxidation -- cobalt -- copper -- hierarchical; Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.202000558
• Languages: English
• ISSNs: 1867-3880

Abstract

Abstract: In order to achieve highly‐efficient water electrolysis, an effective strategy is to design three‐dimensional hierarchical nanostructures by decorating the surface of the main catalysts with co‐catalytic metal compounds. Herein, leave‐like ultrathin Co(OH)2 nanoflakes are grown on branch‐like Cu(OH)2 nanowires via the combination of an anodization process together with an electrodeposition process. The resulting hierarchical Cu(OH)2 @Co(OH)2 nanotrees can be used as efficient OER electrocatalysts with an overpotential as low as 283 mV to reach 10 mA cm −2 . After 20 hours of multi‐current density stability test, the electrode shows negligible degradation while retaining an overpotential of 290 mV to reach 10 mA cm −2, thus showing a high electrocatalytic capability and stability. This work provides a new strategy to improve transition metal electrocatalysts in view of low‐cost water oxidation in alkaline media. Abstract : OER electrocatalysis: A well‐separated hierarchical nanostructure of Cu(OH)2 @Co(OH)2 nanotrees is synthesized through a combination of an anodization process together with an electrodeposition process. The resulting catalysts possess superior solid‐electrolyte interface contact and additional active sites, showing improved electrocatalytic activity as applied to water oxidation in alkaline media. This study provides a new strategy for preparing highly efficient OER catalysts, which could potentially be extended to other electrocatalysis application.